Raman scattering from spin fluctuations in Pr2xCexCuO4y, Nd2xCexCuO4y, and Sm2xCexCuO4y

Abstract
Antiferromagnetic excitations in single crystals of Pr2x Cex CuO4y, Nd2x Cex CuO4y, and Sm2x Cex CuO4y were investigated as a function of Ce concentration using Raman scattering at room temperature. The introduction of electrons by Ce doping significantly broadens the two-magnon peak in the B1g mode, indicating that zone-boundary magnons become damped with increasing Ce concentration. The existence of broad spin-pair-excitation spectra in the B1g and B2g modes at x=0.15 suggests that the short-range spin fluctuations persist in these electron-doped superconductors. The energy of the spin-pair-excitation peak in Pr2x Cex CuO4y is not affected by doping up to x=0.2. This is similar in behavior to the Sm2x Cex CuO4y system up to x=0.17. The absence of softening of the short-wavelength magnons in these systems is in marked contrast to the magnon softening behavior in La2x Srx CuO4y. The Raman spectra in Pr2x Cex CuO4y make no distinction between the superconducting and the metallic regions. The highly damped magnetic-excitation spectra support the picture that the spin-spin correlation length in the present systems decreases gradually with increasing Ce concentration.