Metal to carbene 1,2 hydrogen migration in the protonation of a fischer-type carbene iron(0) complex
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 1182-1185
- https://doi.org/10.1039/c39860001182
Abstract
Protonation of the 1,3-dithiol-2-ylidene iron(0) complex (2a) occurs at the carbene carbon centre, but proceeds via a trans hydrido-carbene intermediate, isomerization into the cis derivative, and metal to carbene carbon 1,2 hydrogen shift.Keywords
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