The electronic structure of conjugated systems II. Unsaturated hydrocarbons and their hetero-derivatives

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Abstract
The theory of Part I (Coulson & Longuet-Higgins 1947) is applied to hydrocarbons and their hetero-derivatives. An equation is given relating differences in activation energy to electron densities and atom polarizabilities (in the sense of Part I) for a heterolytic reaction at different positions in a conjugated system. The equations of Part I are then applied to hydrocarbons containing no odd-membered unsaturated rings. It has previously been shown that in such hydrocarbons all the electron densities are unity, and it is here proved that when one coulomb integral is altered slightly, the electron densities are alternately increased and decreased throughout the molecule. This fact is shown to provide a theoretical basis for the experimental law of alternating polarity in conjugated systems containing a hetero-atom.

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