Molecular "Ghosts"
- 1 November 2002
- journal article
- editorial
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 298 (5595) , 976-977
- https://doi.org/10.1126/science.1078604
Abstract
Molecules can rapidly diffuse through porous materials such as zeolites, but one would not expect them to diffuse through close-packed solids without disturbing the crystal structure of the solid. However, this is precisely what Atwood et al. observed when they dipped a calixarene crystal into vinyl bromide. In his Perspective, Steed predicts that this simple experiment will have tremendous implications for solid-state diffusion, because it is likely that similar processes can occur in other materials. Diffusion is likely to occur through a highly synchronized process.Keywords
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