Measurements of electrical conductivity σ and Hall coefficient RH have been made as a function of temperature in the range room to 500 °C on single crystal n-type tellurium doped samples of GaAs with carrier concentrations in the range 7.9 × 1021 to 4.7 × 1024/m3. Theoretical calculations of σ and RH have been made on a three band (Γ, L, X) model using the method of Fletcher and Butcher and the resulting values fitted to the experimental data by using the temperature coefficients of the band energy differences and various deformation potentials and band coupling coefficients as adjustable parameters. The results confirm the band ordering proposed by Aspnes but give slightly different temperature coefficient values. Values are given for the deformation potentials and band coupling coefficients and in particular the deformation potential of the Γ band is found to be 16.0 ± 0.5 eV.