Réactions primaires de dégradation oxydante au cours de l'autoxydation du poly(oxytétraméthylène) à 25°C, 4 Discussion du schéma réactionnel

Publisher Website
Google Scholar
Abstract
Results from previous publications of the series are interpreted and discussed in terms of a reaction scheme. Probabilities of the different non‐terminating reactions of α‐alkoxyalkylperoxy radicals during the autoxidation of solutions of poly(oxytetramethylene) 10−2 g cm−3 ≤ c ≤ 6.10−2 g cm−3 were determined as follows: for the H atom abstraction = 0,2–0,4, for the monomolecular decomposition (reference) = 1, and for the non‐terminating bimolecular reaction = 7–10.

This publication has 21 references indexed in Scilit: