Synthesis and characterisation of [VS₄(CuPPh₃)₅(CuCl)Cl₂]·CH₂Cl₂; a compound containing a tetrahedral V^vS₄core encapsulated by an octahedral array of copper(I) atoms

1 January 1987

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 23,p. 1749-1750
https://doi.org/10.1039/c39870001749

Abstract

Reaction between [NH₄]₃[VS₄], [NEt₄]Cl, CuCl, and PPh₃ in CH₂Cl₂ has led to the formation of [VS₄(CuPPh₃)₅(CuCl)Cl₂] which contains a hitherto unrecognised type of mixed metal sulphur cluster, consisting of a tetrahedral V^VS₄ core bound to an octahedral array of Cu^I atoms.

Keywords

COPPER

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Synthesis and characterisation of [VS4(CuPPh3)5(CuCl)Cl2]·CH2Cl2; a compound containing a tetrahedral VvS4core encapsulated by an octahedral array of copper(I) atoms

Abstract

Keywords

Synthesis and characterisation of [VS₄(CuPPh₃)₅(CuCl)Cl₂]·CH₂Cl₂; a compound containing a tetrahedral V^vS₄core encapsulated by an octahedral array of copper(I) atoms