An Expeditious Asymmetric Synthesis of (-)-(1R,2S) -Cispentacin
- 1 January 1993
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1993 (07) , 461-462
- https://doi.org/10.1055/s-1993-22490
Abstract
The antifungal antibiotic (-)-(1R,2S) -2-aminocyclopentane-1-carboxylic acid (cispentacin) 4 has been prepared via the highly stereoselective conjugate addition reaction of lithium (S)-(α-methylbenzyl)benzylamide (S)-2 to tert -butyl 1-cyclopentene-1-carboxylate 1.Keywords
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