Studies on Benzothiazoline Derivatives. II. Syntheses of Benzothiazoline Derivatives possessing Substituent Groups at 2- and 3-Positions

Abstract
A general method was established for useful synthesis of benzothiazoline derivatives possessing various functional groups. Reduction of benzothiazolium salts with sodium borohydride in pyridine and reaction of these salts with Grignard agents were examined and many 2,3-disubstituted and 2,2,3-trisubstituted benzothiazoline derivatives were synthesized. Among the benzothiazoline derivatives so obtained, some analgesic and antiinflammatory activities in rats were found using 3-methyl-2-phenyl- and 2,3-dimethyl-2-phenyl-5-benzothiazolineacetic acids.

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