Equation of state for parallel hard spherocylinders
- 1 August 1989
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 40 (3) , 1678-1680
- https://doi.org/10.1103/physreva.40.1678
Abstract
A recent model for positional ordering in systems of monodisperse parallel hard spherocylinders is used to calculate the pressure over the entire range of densities and cylinder axial ratios. Reasonable quantitative agreement with Monte Carlo data is obtained for the full spectrum of nematic, smectic, columnar, and crystalline order. Analytical expressions are also given for the characteristic lengths of the ordering in these phases.Keywords
This publication has 12 references indexed in Scilit:
- Theory of Ordered Phases in a System of Parallel Hard SpherocylindersPhysical Review Letters, 1989
- Equation of state for the hard-sphere gasThe Journal of Chemical Physics, 1988
- A numerical investigation of nematic ordering based on a simple hard-rod modelThe Journal of Chemical Physics, 1987
- Evidence for one-, two-, and three-dimensional order in a system of hard parallel spherocylindersPhysical Review A, 1987
- Evidence for Smectic Order in a Fluid of Hard Parallel SpherocylindersPhysical Review Letters, 1986
- Hard spherocylinders in an anisotropic mean field: A simple model for a nematic liquid crystalThe Journal of Chemical Physics, 1977
- Studies in Molecular Dynamics. V. High-Density Equation of State and Entropy for Hard Disks and SpheresThe Journal of Chemical Physics, 1968
- Theory of the Two- and One-Dimensional Rigid Sphere FluidsThe Journal of Chemical Physics, 1961
- Note on the Free Volume Equation of State for Hard SpheresThe Journal of Chemical Physics, 1952
- The Complete Equation of State of One, Two and Three-Dimensional Gases of Hard Elastic SpheresPhysical Review B, 1936