Dioxygen activation by a neutral β-diketiminato copper(i) ethylene complex

Abstract
The synthesis and structure of two thermally stable neutral β-diketiminato copper(I) olefin complexes are presented along with the structure of a Cu(II)2(μ-OH)2 dimer that results from the reaction of the Cu(I) ethylene complex with O2via the proposed intermediacy of a Cu(III)2(μ-O)2 species.
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