A FACILE SYNTHESIS OF α-C-RIBOFURANOSIDES FROM 1-O-ACETYL RIBOSE IN THE PRESENCE OF TRITYL PERCHLOLATE
- 5 September 1984
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 13 (9) , 1529-1530
- https://doi.org/10.1246/cl.1984.1529
Abstract
In the presence of a catalytic amount of trityl perchlorate, 1-O-acetyl ribose stereoselectively reacts with silylated nucleophiles, such as silyl enol ether, allylsilane, and trimethylsilyl cyanide, to give the corresponding α-C-ribofuranosides in excellent yields.Keywords
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