Covalently supported porphyrins as ligands for the preparation of heme a3/CuB binuclear active site analogues of heme–copper terminal oxidases and metallation under mild conditions

1 January 1998

journal article
Published by Royal Society of Chemistry (RSC) in Chemical Communications

No. 5,p. 571-572
https://doi.org/10.1039/a707785h

Abstract

New covalently supported binucleating porphyrins have been prepared as potential structural and/or functional ligands for the iron–copper (heme a₃/Cu_B) active sites of heme–copper oxidases, and the introduction of iron and copper into one porphyrin under mild reaction conditions has been developed.

Keywords

PORPHYRINS
STRUCTURAL
FUNCTIONAL
HEME
COVALENTLY
BINUCLEATING
TERMINAL
BINUCLEAR
INTRODUCTION
ANALOGUES

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