Photochemical rearrangement of 4H-pyran-4-ones to 2H-pyran-2-ones

Abstract
Irradiation of 2,6-disubstituted-3,5-diphenyl-4H-pyran-4-ones (Ia,b) with a medium-pressure mercury lamp yielded 3,6-diphenyl-4,5-disubstituted-2H-pyran-2-ones (IVa,b).

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