Infrared Spectra of the Group II Halides: Zinc Halides and the Ionic Model
- 1 May 1962
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 36 (9) , 2499-2508
- https://doi.org/10.1063/1.1732915
Abstract
The bending vibrations of gaseous ZnCl2 and ZnBr2 have been observed in the cesium iodide region at 295 and 225 cm—1, respectively. It is shown that a molecular model based on polarizable ions cannot account for the observed bending frequencies of the Group II dihalides.Keywords
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