Palladium-catalysed Synthesis of Perhydroazulenes
- 1 January 1993
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1993 (07) , 539-540
- https://doi.org/10.1055/s-1993-22521
Abstract
Starting from easily accessible α-allylated cycloheptanones, cis- and trans-fused perhydroazulenes have been prepared by palladium-catalysed cyclization of 1,6-enynes. The resulting dienes could be oxidized selectively at either exo-methylene group.Keywords
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