New reactions for use in natural products chemistry
- 1 January 1988
- journal article
- research article
- Published by Walter de Gruyter GmbH in Pure and Applied Chemistry
- Vol. 60 (11) , 1549-1554
- https://doi.org/10.1351/pac198860111549
Abstract
Radicals, generated from isopropylidene uronic esters of N-hydroxy-2-thiopyridone, add readily to electron-poor alkenes in a stereospecific fashion, leading to functionalised chain-elongated furanosides and D-ribo-nucleosides through carbon-4. The directive effect of the ketal group in controlling the newly created chirality is noteworthy.This publication has 4 references indexed in Scilit:
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