Heteronukleare Clustersysteme, X (CO)9Co3M(CO)2(η-C5H6) (M = Mo, W) — Synthese, Eigenschaften und Struktur von Molybdän- und Wolfram-haltigen Trikobaltnonacarbonyl-Clustern / Heteronuclear Cluster Systems, X (CO)9Co3M(CO)2(η-C5H5) (M = Mo, W) — Synthesis, Properties and Structure of Molybdenum and Tungsten Containing Tricobaltnonacarbonyl Clusters
Open Access
- 1 November 1977
- journal article
- research article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 32 (11) , 1277-1283
- https://doi.org/10.1515/znb-1977-1112
Abstract
The synthesis of (CO)3(η-C5H5)M—Co(CO)4 and the cluster-compounds (CO)9Co3M(CO)2(η-C5H5) (M = Mo, W) is described. IR, 1H—NMR and mass spectroscopic data are discussed. The structure of (CO)9Co3Mo(CO)2(η-C5H5) was solved by X-ray analysis.Keywords
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