Reactions of Bis(acetylacetonato)palladium(II) with Triphenylphosphine and Nitrogen Bases

Abstract
Bis (acetylacetonato)palladium (II) reacts with triphenylphosphine and nitrogen bases such as pyridine, diethylamine, and N-methylbenzylamine to transform one of the chelating ligands into the carbon-bonded state. The product complexes of the type Pd(acac)2L have been isolated in high yields and characterized by IR and NMR spectra. Several reactions of Pd(acac)2PPh3 and Pd(acac)2py were also examined.

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