Stereocontrolled Diels–Alder reactions with a bifunctional dienophile
- 1 June 1979
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 57 (11) , 1399-1401
- https://doi.org/10.1139/v79-228
Abstract
In the Diels–Alder cycloaddition of electron-rich dienes to methyl E-4-oxobutenoate, the formyl group controls both regio- and stereoselectivity. Secondary overlap considerations are used to explain these results.Keywords
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