Lithium naphthalenide induced reductive alkylation of α-cyano ketones. A general method for regiocontrol of α, α-dialkylation of ketones
- 11 June 1998
- journal article
- Published by Elsevier in Tetrahedron Letters
- Vol. 39 (24) , 4183-4186
- https://doi.org/10.1016/s0040-4039(98)00780-1
Abstract
No abstract availableKeywords
This publication has 14 references indexed in Scilit:
- Highly Regioselective Alkylation at the More-Hindered α-Site of Unsymmetrical Ketones by the Combined Use of Aluminum Tris(2,6-diphenylphenoxide) and Lithium DiisopropylamideJournal of the American Chemical Society, 1997
- Stereoselective total synthesis of (.+-.)-gymnomitrol via reduction-alkylation of .alpha.-cyano ketonesJournal of the American Chemical Society, 1982
- The kinetically controlled methylation of conjugated polycyclic ketonesTetrahedron, 1974
- New Methods for the Alkylation of Carbonyl CompoundsAngewandte Chemie International Edition in English, 1973
- Reduction and Reductive Alkylation of α-tert-Butylthio Carbonyl Compounds. An Efficient Method for Stepwise α-Alkylation of Esters, Nitriles and Ketones Via the α-Tert-Butylthio DerivativesSynthetic Communications, 1973
- Site-selective geminal alkylation of ketones. Reduction-alkylation of n-butylthiomethylene derivativesJournal of the American Chemical Society, 1971
- Alkylation and Carbonation of Ketones by Trapping the Enolates from the Reduction of α,β-Unsaturated KetonesJournal of the American Chemical Society, 1965
- Alkylations at the α″-Methylene or Methinyl Group of α-Formyl Cyclic Ketones through Their Dicarbanions. Angular Alkylations1Journal of the American Chemical Society, 1965
- Experiments Directed toward the Total Synthesis of Terpenes. III. The Use of trans-Δ6-Octalone-1 in the Preparation of Dicyclic IntermediatesThe Journal of Organic Chemistry, 1962
- The n-Butylthiomethylene Blocking Group1The Journal of Organic Chemistry, 1962