Radical Transfer Hydrosilylation/Cyclization Using Silylated Cyclohexadienes
- 19 June 2001
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 3 (15) , 2357-2360
- https://doi.org/10.1021/ol016160c
Abstract
A new method for mild metal-free hydrosilylation is described. Silylated cyclohexadienes are used as radical transfer hydrosilylating reagents for various double and triple bonds. A trialkylsilane is transferred from a cyclohexadiene moiety to an alkene. The hydrosilylation can be combined with a C−C bond formation as shown for the preparation of silylated cycloalkanes from the corresponding dienes.Keywords
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