Trifluorosilyl derivatives of some transition elements

Abstract
The compounds F3SiMn(CO)5, F3SiMn(CO)4PPh3, F3SiRe(CO)5, F3SiFe- (π- C5H5)(CO)2, and F3SiMo(W)(π-C5H5)(CO)3 have been prepared by the reaction of SiF3H with appropriate binuclear carbonyls. The infrared, mass, and 19F n.m.r, spectra for the compounds are discussed, together with some chemical properties.

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