Versatility of cycloaddition of electrophilic alkynes to η2-CS2metal complexes. Reversible isomerisation of 1,3-dithiol-2-ylideneiron and heterometallocyclic complexes
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 573-574
- https://doi.org/10.1039/c39780000573
Abstract
The 1,3-dithiol-2-ylideneiron(0) complexes (3) isomerise to heterometallocycles (4), the equilibrium constant and rate constant increasing with donor strengths of the ligands on iron.Keywords
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