The nitrogen-15 n.m.r. criterion of bond angle in nitrosyl complexes
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 125-126
- https://doi.org/10.1039/c39830000125
Abstract
Deshielding of 350–700 p.p.m. is reported for nitrogen in strongly bent nitrosyl groups (∠MNO ca. 120°) in complexes of Rh or Co, compared with linear nitrosyl groups in complexes of Fe, Co, Ru, and other transition metals.Keywords
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