Modelling the photosynthetic water oxidation centre: synthesis, structure, and magnetic properties of [Mn4O2(OAc)7(biphy)2ClO4]·3H2O (bipy = 2,2′-bipyridine)
- 1 January 1987
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 236-238
- https://doi.org/10.1039/c39870000236
Abstract
The synthesis, structure, and magnetic properties of [Mn4O2(OAc)7(bipy)2](ClO4)·3H2O, bipy = 2,2′-bipyridine) are reported; this complex is the first tetranuclear oxide-bridged manganese(III) species and represents the best available model for the photosynthetic water oxidation centre.Keywords
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