Cis-Trans Isomerism among the Octahedral Anionobis(C-substituted ethylenediamine)nickel(II) Complexes Obtained by Thermal Reactions
Open Access
- 1 June 1986
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 59 (6) , 1825-1827
- https://doi.org/10.1246/bcsj.59.1825
Abstract
Ten octahedral anionobis(C-substituted ethylenediamine)nickel(II) complexes were obtained by thermal reactions of corresponding diaqua salts, and their electronic and IR spectra were examined to see whether they are cis or trans. Most of them were found to be trans, but [Ni(NO3)(m-bn)2](NO3) and [NiCl2(i-bn)2] were cisKeywords
This publication has 16 references indexed in Scilit:
- Thermal square planar-to-octahedral transformation of nickel(II) complexes containing butanediamines in a solid phaseThermochimica Acta, 1983
- Analytical treatment of the electronic spectra of some low-symmetry transition metal complexesCoordination Chemistry Reviews, 1982
- The single crystal electronic spectra of cis-octahedral nickel(II) diamine complexes at 10 KCanadian Journal of Chemistry, 1982
- The single crystal polarised electronic spectrum of all-trans Ni(as-N,N-dimethylethylenediamine)2(trichloroacetate)2 at 10 KInorganica Chimica Acta, 1980
- The electronic spectra of coordinated nitrite ion: correlation between spectra and structureCanadian Journal of Chemistry, 1980
- The Low Temperature Polarised Electronic Spectra of Some Tetragonal Nickel(II) Haloacetate ComplexesSpectroscopy Letters, 1979
- Single crystal electronic spectra of a series of trans nickel(II) complexes with N,N′-diethyl- and N,N′-dimethylethylenediamineCanadian Journal of Chemistry, 1977
- The spectrochemical properties of tetragonal complexes of high spin nickel(II) containing macrocyclic ligandsJournal of the American Chemical Society, 1977
- The Derivation and Application of Normalized Spherical Harmonic HamiltoniansPublished by Wiley ,1977
- Single crystal electronic spectra and ligand field parameters of some nickel(II) amine-isothiocyanato and amine-nitrito complexesInorganic Chemistry, 1976