A Functional Organic Battery
- 22 June 2007
- journal article
- synthesis of-materials-and-unnatural-products
- Published by Georg Thieme Verlag KG in Synfacts
- Vol. 2007 (7) , 0710
- https://doi.org/10.1055/s-2007-968652
Abstract
An organic battery was constructed using polymer P1, which contains a high density of pendant nitroxide radical functional groups. The reversible electrochemical formation of the oxoammonium cation from a nitroxide radical forms the basis of charge storage in this battery. To avoid dissolving the polymer in an electrolyte solution while fabricating the battery, a radical-compatible photocrosslinking strategy was developed using a bisazide photocrosslinker. Using this strategy, cathode-active films of P1 were produced and the resulting battery could be reversibly charged and discharged for up to 1000 cycles.Keywords
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