Insertion of acetylenes into carbon–titanium σ-bonds

Abstract
Photochemically induced reactions between [(η5-C5H5)2TiMe2] and either diphenylacetylene or bis(pentafluorophenyl)acetylene have been shown to produce σ-methylstilbenyltitanium derivatives resulting from insertions of these alkynes into the methyltitanium σ-bond.
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