Synthesis and crystal structure of an analogue of the uranyl(VI) ion, containing a linear OUN– group
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 2601-2602
- https://doi.org/10.1039/c39940002601
Abstract
The crystal structure of the air-stable compound PPh4 +[UOCl4{NP(m-Tol)3}]–(m-Tol = C6H4Me-m) shows that it contains a linear (179°) OUN–group, with U–O and U–N distances of 176 and 190 pm respectively, coordinated by four chlorine atoms; the U–O distance is typical of uranyl compounds, and the U–N distance suggests a bond order >2.Keywords
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