Selective skeletal rearrangement by carbon–carbon bond activation
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 182-183
- https://doi.org/10.1039/c39900000182
Abstract
Skeletal rearrangement of α-substituted organometallic compounds to give β-substituted compounds by carbon-carbon bond activation was performed with bis(η5-cyclopentadienyl)-2,5-dimethyl-zircons- or -hafna-cyclopentane, which were regio- and stereo-selectively converted into the corresponding 3,4-dimethylmetallacyclopentanes in high yield.Keywords
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