Electronic Raman Effect. II. Asymmetry of the Scattering Tensor for Electronic Raman Transitions
- 1 May 1968
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 48 (9) , 3971-3977
- https://doi.org/10.1063/1.1669722
Abstract
The theory of electronic Raman scattering for trivalent rare‐earth ions in crystals is formulated in a general way. It is shown that vibronic coupling is unimportant. The antisymmetric part of the scattering tensor, which vanishes for vibrational Raman scattering, turns out to be dominant for several electronic Raman transitions. The implications of this with respect to selection rules and depolarization ratios are pointed out.Keywords
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