Chemistry of the solanidane ring system
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society C: Organic
- p. 149-152
- https://doi.org/10.1039/j39710000149
Abstract
The reaction of acetyldemissidine and acetylsolanidine with cyanogen bromide is described and the results of the lithium aluminium hydride reduction of the bromo-cyanamides so produced are discussed. The hydrolysis of acetyldemissidine bromo-cyanamide under very mild conditions caused a retro-von Braun reaction to afford the initial alkaloid.Keywords
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