Measurement of Anharmonic Renormalization of Phonon Frequencies

Abstract
The shift and broadening of several phonon modes in KCl and RbCl have been measured as a function of temperature from 10 to 400°K by means of first-order Raman spectra induced by Tl+ impurities. Mode Grüneisen parameters are computed for the major phonon frequencies which contribute to the Raman spectra. These dominant phonons lie near the zone boundary.

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