A novel route to efficient inorganic oxide surface modifications: molecularly self-assembled linear and conjugated alkynyl thin film materials
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 907-909
- https://doi.org/10.1039/c39950000907
Abstract
Treatment of surface hydroxy groups on glass, quartz and single crystal silicon with commercially available group 14 chlorides, ECl4(E = Si, Sn), and then NEt2H yields surface-anchored NEt2 moieties, which react with several organic molecules containing terminal acidic protons, including rigid-rod alkynes, via acid–base hydrolysis, leading to molecularly self-assembled chromophoric monolayers.Keywords
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