Corrections to O((lnα)) fine-structure splittings and O((lnα)) energy levels in helium
- 1 August 1996
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 54 (2) , 1252-1312
- https://doi.org/10.1103/physreva.54.1252
Abstract
Fully relativistic formulas for the energy-level shifts arising from no-pair exchange diagrams of two transverse photons plus an arbitrary number of Coulomb photons are derived in closed form within the external potential Bethe-Salpeter formalism. O((lnα)) corrections to the fine-structure splittings of helium are obtained and expressed in terms of expectation values of nonrelativistic operators. O( ) operators from exchange diagrams are found in nonrelativistic approximation. O( /M) nucleus-electron operators contributing to the fine-structure splittings are derived. Nonrelativistic operators of O( ) corrections to the triplet levels of helium are presented. Nonrelativistic operators of O((lnα)) corrections to the helium singlet levels and to positronium S levels are derived. O( /M) hydrogen and O( ) positronium P levels, and O((lnα)) corrections of first order to positronium S levels, are calculated using the derived operators for helium, in agreement with those obtained previously by others, except for one term in corrections to positronium P levels. In addition, the O( ) Dirac energies for hydrogenic non-S levels are exactly reproduced in a perturbative calculation. © 1996 The American Physical Society.
Keywords
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