Chiral interactions in aqueous solution mediated by lanthanoid ions. N.m.r. spectral resolution of enantiomeric nuclei
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 68-69
- https://doi.org/10.1039/c39790000068
Abstract
The 1 : 1 lanthanoid complexes with chiral α-hydroxycarboxylate ligands act as aqueous chiral n.m.r. shift reagents by stereospecifically forming 1 : 2 complexes, thereby resolving the resonances of enantiomeric mixtures and of enantiotopic protons.Keywords
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