Novel stannosilicates. Part 1. Synthesis and characterisation

Abstract
New phases of sodium stannosilicate have been prepared by hydrothermal methods. One of these is crystalline with a very unusual habit. It has the composition Na2O·1.38 SnO2·2.05 SiO2·2H2O. Its synthesis and characterisation by chemical and thermal analysis are described. Additional information has been drawn from X-ray diffraction, scanning electron microscopy as well as Mössbauer and magic angle spinning n.m.r. spectroscopy.

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