Effect of medium on dissociation of carboxylic acids
- 1 January 1985
- journal article
- Published by Institute of Organic Chemistry & Biochemistry in Collection of Czechoslovak Chemical Communications
- Vol. 50 (12) , 2670-2678
- https://doi.org/10.1135/cccc19852670
Abstract
PK Values of carboxylic acids have been measured in mixtures water-organic solvent and confronted with the Born equation. Solubilities of benzoic acid have been measured. From the pK and solubilities found the ΔGt0(C6H5COO-) values have been calculated for various two-component solvents. The results agree with the idea that the ion transfer into another medium is affected not only by electrostatic, but also by non-electrostatic forces.Keywords
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