Barbier-type allylation of aldehydes mediated by antimony(III) chloride–metallic iron or antimony(III) chloride–metallic aluminium
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 2,p. 424-425
- https://doi.org/10.1039/p19900000424
Abstract
Active zero-valent antimony generated from antimony(III) chloride–metallic iron or antimony(III) chloride–metallic aluminium, induced allylation of aldehydes with allylic halides at room temperature to give high yields of the corresponding homoallylic alcohols with high regio- and chemo- selectivity.Keywords
This publication has 12 references indexed in Scilit:
- Barbier-Grignard-type allylation of aldehydes with metallic antimonyTetrahedron Letters, 1987
- Bismuth(III) chloride–aluminium-promoted allylation of aldehydes to homoallylic alcohols in aqueous solventJournal of the Chemical Society, Chemical Communications, 1987
- Carbon—carbon bond formation with bismuth salt. A chemoselective Grignard-type addition of allyl unit to aldehydesTetrahedron Letters, 1986
- Allylzinc reagents additions in aqueous mediaThe Journal of Organic Chemistry, 1985
- Metallic bismuth mediated allylation of aldehydes to homoallylic alcoholsTetrahedron Letters, 1985
- Carbon-carbon bond-forming reactions using cerium metal or organocerium(III) reagentsThe Journal of Organic Chemistry, 1984
- Grignard-type allylation of carbonyl compounds in methanol by the electrochemically recycled allyltin reagent.Tetrahedron Letters, 1984
- CARBON–CARBON BOND FORMATION WITH METALLIC MANGANESEChemistry Letters, 1983
- Allylation of aldehydes and ketones in the presence of water by allylic bromides, metallic tin, and aluminumOrganometallics, 1983
- AN EFFICIENT SYNTHESIS OF HOMOALLYL ALCOHOLS BY THE REACTION OF ALLYL HALIDES WITH CARBONYL COMPOUNDS IN THE PRESENCE OF METALLIC TINChemistry Letters, 1981