Syntheses and Properties of Heterodinuclear μ-Ethynediyl Complexes Containing Palladium and Platinum
- 1 April 1992
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 65 (4) , 1179-1181
- https://doi.org/10.1246/bcsj.65.1179
Abstract
Heterodinuclear μ-ethynediyl complexes Cl(R3P)2MC≡CM′(PR3)2Cl (3) (M = Pt, M′ = Pd; R = Me, Et, n-Bu) were prepared by the reactions of chloroethynylbis(trialkylphosphine)platinum (1) with dichlorobis(trialkylphosphine)palladium (2) in the presence of CuCl catalyst. These complexes were fully characterized by mass, 13C{1H}, and 31P{1H} NMR spectroscopies.Keywords
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