Observation of second-harmonic generation from a Langmuir-Blodgett monolayer of a merocyanine dye

Abstract
Second-harmonic generation (SHG) from a merocyanine dye Langmuir-Blodgett monolayer is reported. Values for the second-order molecular polarisability β and its average orientation within the layer are deduced. Extinction of the SHG is observed for symmetrical bilayers. Protonation of a dye monolayer is seen to suppress SHG.

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