ChemInform Abstract: Trifluoromethanethiolate Ion. Part 2. Nucleophilic Substitution in Pentafluoropyridine. Synthesis and Characteristics of Trifluoromethylthio and Trifluoromethylsulfonyl Derivatives.
- 26 January 1988
- journal article
- other
- Published by Wiley in ChemInform
- Vol. 19 (4)
- https://doi.org/10.1002/chin.198804213
Abstract
The CF3S‐ anion, generated from the species (II) or its trimer (III) and CsF, reacts with pentafluoropyridine (Ia) to give the derivative (Ib) which reacts further to give the compounds (IVa) + (IVb) + (IVc) when the system B) is used.Keywords
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- Trifluoromethanethiolate ion. Part 2. Nucleophilic substitution in pentafluoropyridine. Synthesis and characteristics of trifluoromethylthio and trifluoromethylsulphonyl derivativesJournal of the Chemical Society, Perkin Transactions 1, 1987