Radiative decay of multiply excited core hole states in H2O
- 15 May 1985
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 82 (10) , 4486-4491
- https://doi.org/10.1063/1.448701
Abstract
A high resolution x-ray emission spectrum of water vapor has been recorded, using a 7 keV electron beam and a 10 m grazing incidence spectrometer. The spectrum is interpreted in terms of dipole transition moments between CI wave functions built from separately optimized molecular orbitals. The principal features of the spectrum are reproduced considering transitions in the singly and doubly ionized species, giving rise to main lines and Wentzel–Druyvesteyn satellites, respectively.Keywords
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