REACTION AND STEREOCHEMISTRY OF 1,2,3-TRITHIANE RING
- 5 November 1978
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 7 (11) , 1219-1222
- https://doi.org/10.1246/cl.1978.1219
Abstract
Oxidative desulfurization of 5-hydroxy-1,2,3-trithiane affords cis- and trans-4-hydroxy-1,2-dithiolane-1-oxide. X-Ray structure determination of 1,2,3-trithian-5-yl N-methylcarbamate reveals that the trithiane ring takes a chair conformation with S–S = 2.040(4) Å(av), S–S–S = 101.5(3)°, and S–S–C = 98.6(3)°(av), and that the side chain places in the equatorial position.Keywords
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