Syntheses and reactivity of cofacial, dimeric metal–metal bonded ruthenium(II) mixed valence ruthenium(II/III), and ruthenium(III) complexes of [C22H22N4]2–, a dibenzo-tetra-aza[14]annulene ligand
- 1 January 1978
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 909-910
- https://doi.org/10.1039/c39780000909
Abstract
A novel series of metal–metal bonded RuII, mixed valence RuII/III, and RuIII complexes [Ru(C22H22N4)]2 n+, of a dibenzotetra-aza[14]annulene ligand have been isolated and characterized which possess ground spin-triplet, spin-doublet, and singlet states, respectively.Keywords
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