Carbaborane salts of [ZnCl(HpztBu)3]+, a host for inorganic anions (HpztBu = 5-tert-butylpyrazole)
- 1 January 2002
- journal article
- Published by Royal Society of Chemistry (RSC) in New Journal of Chemistry
- Vol. 26 (11) , 1634-1637
- https://doi.org/10.1039/b207966f
Abstract
The cations in [ZnCl(HpztBu)3]Y (Y− =[Co(C2B9H11)2]− or [1-Ph-closo-1-CB9H9]−) associate into dimers in the crystal, presenting a bowl-shaped face into which the carbaborane anions can pack. In contrast, the cations in [ZnCl(HpztBu)3][6,7,8,9,10-Br5-closo-1-CB9H5]·H2O associate with each other into a 1-D hydrogen-bonded polymer.Keywords
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