Dichotomous reactions of thioketones with tetracarbonylferrate
- 1 March 1979
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 57 (5) , 598-600
- https://doi.org/10.1139/v79-096
Abstract
Treatment of nonenolizable and enolizable thioketones, first with disodium tetracarbonylferrate and then with an acid chloride, affords saturated and unsaturated thioesters, respectively. Mechanisms are proposed for these different reactions.Keywords
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