Synthesis of (−)‐Conduritol C (1L‐Cyclohex‐5‐ene‐1,2,3/4‐tetrol)
- 15 March 1989
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 72 (2) , 338-347
- https://doi.org/10.1002/hlca.19890720219
Abstract
(1R, 2R, 4R)‐2‐endo‐Cyano‐7‐oxabicyclo[2.2.1]hept‐5‐en‐2‐yl acetate ((−)‐7) has been transformed into the all‐cis‐configurated 4L‐4,5,6/0‐trihydroxycyclohex‐2‐en‐1‐one derivatives (−)‐12 and (−)‐19. (−)‐Conduritol C ((−)‐3) was derived in a stereospecific manner from (−)‐12.Keywords
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