Analysis of Chlorinated Aromatic Hydrocarbons by Exhaustive Chlorination: Qualitative and Structural Aspects of the Perchloro-Derivatives of Biphenyl, Naphthalene, Terphenyl, Dibenzofuran, Dibenzodioxin and DDE
- 1 November 1972
- journal article
- research article
- Published by Taylor & Francis in International Journal of Environmental Analytical Chemistry
- Vol. 2 (2) , 95-106
- https://doi.org/10.1080/03067317208073249
Abstract
A number of reagents for the exhaustive chlorination of aromatic compounds were investigated. Antimony pentachloride-iodine, and the BMC reagent (sulfuryl chloride-aluminum chloride-disulfur dichloride) were found to be the most effective and convenient reagents. They are liquids which can be used without special precautions to prepare the perchloro-derivatives of biphenyl, terphenyl, naphthalene, dibenzofuran, dibenzodioxin and DDE. The structures, mass spectra and GLC properties of these compounds are discussedKeywords
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